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The Cast of The CWs VALENTINE. Pictured (L-R) Kristoffer Polaha as Valentine, Autumn Reeser as Phoebe Valentine , Robert Baker as Leo and Jaime Murray as Grace Valentine star in the CW new comedy VALENTINE premiering September 21, 8:00-9:00 PM on The CW. Photo: Sonja Flemming/CBS. ©2008 The CW Network, LLC. All Rights Reserved.